Consider the following reaction. The product $X$ is used:

  • A
    in acid base titration as an indicator
  • B
    in protein estimation as an alternative to ninhydrin
  • C
    in laboratory test for phenols
  • D
    as food grade colourant

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Rank the following in decreasing order of their acidic strengths:
$(A)$ Tetrahydrofuran-oxonium ion
$(B)$ Pyrrolidine
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$(D)$ $N$-methylpyrrolidinium ion

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The major product $B$ in the following reaction sequence is:
$CH_3-CH_2-CH(CH_3)-CONH_2$ $\xrightarrow{Br_2/KOH, \Delta} (A)$ $\xrightarrow{(1) CH_3I (excess), (2) AgOH/\Delta} (B)$

Which gas will be evolved out when $[CH_3CH_2NH_2 + (CH_3)_2CHNH_2]$ is treated with sodium nitrite and $HCl$?

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